Chromium (Cr)

Atomic number: 24
Atomic weight: 51.996
Average concentration in ocean: 4.0 nmol/kg
Residence time: 8000 years


Distribution in ocean
Chromium is slightly depleted at the surface and the vertical concentration  profile increases with depth (data). 

Speciation
Chromium exists in seawater primarily in the +VI oxidation state as the chromate, CrO42-, ion.  Detectable amounts of chromium in the +III oxidation state are also present as Cr(OH)2+ and Cr(OH)30.

Residence time
The chromium residence time is from Tracers in the Sea (Broecker, W. S. and Peng, T.-H., 1982.  Eldigo Press, Palisades, NY).  It was calculated from the global average river input.

Analysis
Chromium is concentrated by coprecipitation with iron hydroxide and then determined by graphite furnace atomic absorption spectrophotometry or by isotope dilution mass spectrometry.

References